Hydrothermal Fluid Sources of the Fengjia Barite–fluorite Deposit in Southeast Sichuan,China: Evidence from Fluid Inclusions and Hydrogen and Oxygen Isotopes          下载免费PDF全文

Hao Zou  Shou‐ting Zhang  An‐qing Chen  Yi Fang  Zhao‐fa Zeng 《Resource Geology》2016,66(1):24-36

The Fengjia barite–fluorite deposit in southeast Sichuan is a stratabound ore deposit which occurs mainly in Lower Ordovician carbonate rocks. Here we present results from fluid inclusion and oxygen and hydrogen isotope studies to determine the nature and origin of the hydrothermal fluids that generated the deposit. The temperature of the ore‐forming fluid shows a range of 86 to 302 °C. Our detailed microthermometric data show that the temperature during mineralization of the fluorite and barite in the early ore‐forming stage was higher than that during the formation of the calcite in the late ore‐forming stage. The salinity varied substantially from 0.18% to 21.19% NaCl eqv., whereas the density was around 1.00 g/cm³. The fluid composition was mainly H₂O (>91.33%), followed by CO₂, CH₄ and traces of C₂H₆, CO, Ar, and H₂S. The dominant cation was Na⁺ and the dominant anion Cl^‐, followed by Ca²⁺, SO₄^2‐, K⁺, and Mg²⁺, indicating a mid–low‐temperature, mid‐low‐salinity, low‐density NaCl–H₂O system. Our results demonstrate that the temperature decreased during the ore‐forming process and the fluid system changed from a closed reducing environment to an open oxidizing environment. The hydrogen and oxygen isotope data demonstrate that the hydrothermal fluids in the study area had multiple sources, primarily formation water, as well as meteoric water and metamorphic water. Combined with the geological setting and mineralization features we infer that the stratabound barite–fluorite deposits originated from mid–low‐temperature hydrothermal fluids and formed vein filling in the fault zone.  相似文献   

青藏高原晚始新世干旱化事件：改则盆地康托组碳酸盐岩碳氧同位素的记录     

姜高磊  徐亚东  宋博文  张克信  罗亮 《地质学报》2016,90(8):2023-2034

改则盆地位于青藏高原腹地,盆地内沉积物记录了高原古环境变化的重要信息。本文对改则盆地康托组碳酸盐岩碳氧同位素进行研究,结果显示改则盆地中-晚始新世的演化分为两个阶段:1中始新世湿润气候下开放湖盆阶段:虽然碳酸盐岩δ~(18)O值在43层处向正值偏移,但整体~(18)O和~(13)C强烈亏损,并且该时期碳酸盐岩δ~(18)O值和δ~(13)C变化相关系数为R~2=0.082。表明该阶段的研究区虽然经历过短期蒸发作用增强或补给水减少,但整体是气候湿润条件下补给水丰富的开放型湖盆。2晚始新世干旱气候下封闭湖盆阶段:经过中新世晚期(63层)气候和湖泊水文状态的过渡,晚始新世~(18)O和~(13)C同位素富集,δ~(18)O值和δ~(13)C值变化相关系数为R~2=0.7762。表明该阶段气候干旱,蒸发作用强烈,湖盆萎缩成为封闭湖盆。综合前人研究,认为青藏高原腹地及北缘、东北缘在晚始新世存在明显的区域性干旱化事件。对比分析青藏高原隆升、全球气候记录、全球海水Sr和大气CO_2记录,认为青藏高原腹地和北部的干旱化事件主要受青藏高原隆升的影响。  相似文献   

青藏铁路建设环境的"三大难题"     

许兆义  李宁  魏静 《吉林大学学报(地球科学版)》2007,37(2):406-410

青藏铁路是世界上第一条跨越高原多年冻土区的铁路,工程建设环境面临多年冻土、高寒缺氧、生态脆弱的“三大难题”,比国内外其他多年冻土工程建设更艰巨和困难。由于青藏铁路建设环境的特殊性与复杂性,设计和建设中采取了多种保护冻土的有效措施、高原劳动卫生和劳动保护措施及生态环境保护措施及污染防治措施,各项措施在青藏铁路的建设和运营中显示出了良好的效果。  相似文献   

The importance of oxygen isotope provenance in relation to solute content of bulk meltwaters at Imersuaq Glacier,West Greenland     

Jacob C. Yde  N. Tvis Knudsen 《水文研究》2004,18(1):125-139

Stable oxygen isotope analysis and measurement of several dissolved cations and anions of bulk meltwater samples have provided information about the hydrochemical environment of the glacial hydrological system at Imersuaq Glacier, an outlet tongue from the Greenland ice‐sheet, West Greenland. The samples were collected at frequent intervals during the period 20–28 July 2000 in a small (<20 L s^?1) englacial meltwater outlet at the glacier margin. The results document the following findings: (i) a marked diurnal variation of δ¹⁸O is related to the composition of oxygen isotope provenances, mainly near‐marginal local superimposed ice and basal up‐sheared ice further up‐glacier; (ii) a relationship is seen between all base cations (Na⁺, K⁺, Ca²⁺, Mg²⁺), SO₄^2? and δ¹⁸O, indicating that solute acquisition is provided by solid–solution contact with the up‐sheared ice—as the relationship with Cl^? is weak the influence of seasalt‐derived solutes is small in the area; (iii) when the melt rate is high, two diurnal maxima of δ¹⁸O values and solute concentrations are measured, and it is suggested that a snow meltwater component is responsible for the second maximum of δ¹⁸O—a short residence time leads to a delayed decrease in ion concentrations. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Overview of In - Situ Biodegradation and Enhancement     

DONG Jun  Anthony Adzomani  Zhao Yongsheng 《世界地质(英文版)》2002,5(1)

Microbial degradation technologies have been developed to restore ground water quality in aquifers polluted by organic contaminants effectively in recent years. However, in course of the degradation, the formation of biofilms in ground water remediation technology can be detrimental to the effectiveness of a ground water remediation project. Several alternatives are available to a remedial design engineer, such as Permeable Reactive Barriers (PRBs) and in -situ bioremediation, Hydrogen Releasing Compounds (HRCs) barrier, Oxygen Releasing Compounds (ORCs) barrier etc. which are efficient and cost- effective technologies. Excessive biomass formation renders a barrier ineffective in degrading the contaminants, Efforts are made to develop kinetics models which accurately determine bio - fouling and bio - filn formation and to control excessive biomass formation.  相似文献   

Oxygen isotopes composition of sapphires from the French Massif Central: implications for the origin of gem corundum in basaltic fields     

Gaston?GiulianiEmail author  Anthony?Fallick  Daniel?Ohnenstetter  Guy?Pegere 《Mineralium Deposita》2009,44(2):221-231

Alluvial and colluvial gem sapphires are common in the basaltic fields of the French Massif Central (FMC) but sapphire-bearing xenoliths are very rare, found only in the Menet trachytic cone in Cantal. The O-isotope composition of the sapphires ranges between 4.4 and 13.9‰. Two distinct groups have been defined: the first with a restricted isotopic range between 4.4 and 6.8‰ (n = 22; mean δ¹⁸O = 5.6 ± 0.7‰), falls within the worldwide range defined for blue-green-yellow sapphires related to basaltic gem fields (3.0 < δ¹⁸O < 8.2‰, n = 150), and overlaps the ranges defined for magmatic sapphires in syenite (4.4 < δ¹⁸O < 8.3‰, n = 29). A second group, with an isotopic range between 7.6 and 13.9‰ (n = 9), suggests a metamorphic sapphire source such as biotite schist in gneisses or skarns. The δ¹⁸O values of 4.4–4.5‰ for the blue sapphire-bearing anorthoclasite xenolith from Menet is lower than the δ¹⁸O values obtained for anorthoclase (7.7–7.9‰), but suggest that these sapphires were derived from an igneous reservoir in the subcontinental spinel lherzolitic mantle of the FMC. The presence of inclusions of columbite-group minerals, pyrochlore, Nb-bearing rutile, and thorite in these sapphires provides an additional argument for a magmatic origin. In the FMC lithospheric mantle, felsic melts crystallized to form anorthoclasites, the most evolved peraluminous variant of the alkaline basaltic melt. The O-isotopic compositions of the first group suggests that these sapphires crystallized from felsic magmas under upper mantle conditions. The second group of isotopic values, typified for example by the Le Bras sapphire with a δ¹⁸O of 13.9‰, indicates that metamorphic sapphires from granulites were transported to the surface by basaltic magma.  相似文献   

Using ocean quahog (<Emphasis Type="Italic">Arctica islandica</Emphasis>) shells to reconstruct palaeoenvironment in Öresund,Kattegat and Skagerrak,Sweden     

Elena Dunca  Harry Mutvei  Peter Göransson  Carl-Magnus Mörth  Bernd R. Schöne  Martin J. Whitehouse  Mikael Elfman  Susanne P. Baden 《International Journal of Earth Sciences》2009,98(1):3-17

Shells of Arctica islandica collected between 1884 and 2004 from Öresund, Kattegat and Skagerrak (Swedish West Coast) were used to monitor local climate variations and the influence of human activities on the local environment. For this purpose, we analysed the growth, structure and chemical composition of these shells and compared them with shells collected from Kiel Bay, Norway and Iceland. The growth rate of the studied shells registers an NAO periodicity of ca 8 years. However, the observed signal is weak because of other environmental interferences that are either of natural or anthropogenic origin. For example, the oxygen isotope ratios show temperature fluctuation, but also the influx of low salinity water. Higher contents of S, N, Cu, Zn, As, Cd and P in shell portions formed during the last century are related to human activities such as mining and industrial development. Our study indicates that in order to use Arctica shells as archives of climate change it is necessary to study the full range of environmental data that is recorded in the shells by using a multi element and isotope approach in combination with different analytical techniques including investigation of growth rates and shell structure.  相似文献   

Rapid macrofaunal colonization of water-based drill cuttings on different sediments     

Trannum HC  Setvik S  Norling K  Nilsson HC 《Marine pollution bulletin》2011,62(10):2145-2156

A field experiment was conducted to investigate how water-based drill cuttings and sediment type influence colonization of soft bottom communities. Bottom frames with trays containing defaunated sediments were placed at the seabed for 6 months to study colonization of macrofauna. Two different sediments (coarse and fine) were used, and 6 or 24 mm layer of water-based drill cuttings were added on top of these sediments. Some of the sediments were controls with no additions. In the end of the experiment, the oxygen availability in sediment porewater and macrofaunal abundance were reduced in treatments with 24 mm drill cuttings compared to controls. Tube-building annelids were particularly sensitive to drill cuttings. However, these responses were only minor, and notably, the drill cuttings initiated a weaker faunal response than sediment type and site of the bottom frame. Sediments capped with water-based drill cuttings thus showed a rapid colonization of macrofaunal communities.  相似文献   

Critical soil conditions for oxygen stress to plant roots: Substituting the Feddes-function by a process-based model     

Ruud P. Bartholomeus  Jan-Philip M. Witte  Peter M. van Bodegom  Jos C. van Dam  Rien Aerts   《Journal of Hydrology》2008,360(1-4):147-165

Effects of insufficient soil aeration on the functioning of plants form an important field of research. A well-known and frequently used utility to express oxygen stress experienced by plants is the Feddes-function. This function reduces root water uptake linearly between two constant pressure heads, representing threshold values for minimum and maximum oxygen deficiency. However, the correctness of this expression has never been evaluated and constant critical values for oxygen stress are likely to be inappropriate. On theoretical grounds it is expected that oxygen stress depends on various abiotic and biotic factors. In this paper, we propose a fundamentally different approach to assess oxygen stress: we built a plant physiological and soil physical process-based model to calculate the minimum gas filled porosity of the soil (_{gas_min}) at which oxygen stress occurs.First, we calculated the minimum oxygen concentration in the gas phase of the soil needed to sustain the roots through (micro-scale) diffusion with just enough oxygen to respire. Subsequently, _{gas_min} that corresponds to this minimum oxygen concentration was calculated from diffusion from the atmosphere through the soil (macro-scale).We analyzed the validity of constant critical values to represent oxygen stress in terms of _{gas_min}, based on model simulations in which we distinguished different soil types and in which we varied temperature, organic matter content, soil depth and plant characteristics. Furthermore, in order to compare our model results with the Feddes-function, we linked root oxygen stress to root water uptake (through the sink term variable F, which is the ratio of actual and potential uptake).The simulations showed that _{gas_min} is especially sensitive to soil temperature, plant characteristics (root dry weight and maintenance respiration coefficient) and soil depth but hardly to soil organic matter content. Moreover, _{gas_min} varied considerably between soil types and was larger in sandy soils than in clayey soils. We demonstrated that F of the Feddes-function indeed decreases approximately linearly, but that actual oxygen stress already starts at drier conditions than according to the Feddes-function. How much drier is depended on the factors indicated above. Thus, the Feddes-function might cause large errors in the prediction of transpiration reduction and growth reduction through oxygen stress.We made our method easily accessible to others by implementing it in SWAP, a user-friendly soil water model that is coupled to plant growth. Since constant values for _{gas_min} in plant and hydrological modeling appeared to be inappropriate, an integrated approach, including both physiological and physical processes, should be used instead. Therefore, we advocate using our method in all situations where oxygen stress could occur.  相似文献   

Progress in isotope paleohydrology using lake sediment cellulose     

Brent B. Wolfe  Matthew D. Falcone  Ken P. Clogg-Wright  Cherie L. Mongeon  Yi Yi  Bronwyn E. Brock  Natalie A. St. Amour  William A. Mark  Thomas W. D. Edwards 《Journal of Paleolimnology》2007,37(2):221-231

Recent advances in sample preparation techniques and mass spectrometry have fostered more routine oxygen isotope analysis of aquatic cellulose in lake sediment cores, a proxy for lake water oxygen isotope history. These methodological developments have significantly increased the feasibility of incorporating this approach into high-resolution, multi-site, and multi-proxy studies, which are frequently necessary to answer complex hydrological, hydroecological and hydroclimatic questions requiring a paleoenvironmental perspective. Direct translation of lake sediment aquatic cellulose oxygen isotope composition into lake water oxygen isotope composition offers appreciable opportunity for quantitative paleohydrological reconstructions, as evidenced by studies conducted over the past 15 years that span Holocene and pre-historical timescales.  相似文献